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Ecoprofile of perborates

5. Ecoprofile results

This section presents the results of the ecoprofile calculations. The background to ecoprofile calculations in general, the specific assumptions used in this work and some guidance on the interpretation of the tables are given in Appendix 1.

5.1. Energy

The gross or cumulative energy associated with the production of sodium perborate tetrahydrate is shown in Table 1 and the corresponding data for the monohydrate is given in Table 2.

Table 1.
Gross energy associated with the production of 1 kg of sodium perborate tetrahydrate.

Fuel type   Production & delivery Delivered energy Transport Feedstock energy Total energy energy
Electricity/MJ 4.17 1.84 0.04 0.00 6.05
Oil fuels/MJ 0.24 0.95 0.66 0.02 1.86
Other fuels/MJ 0.46 6.40 0.00 0.05 6.91
Total/MJ 4.87 9.19 0.71 0.07 14.83

Table 2.
Gross energy associated with the production of 1 kg of sodium perborate monohydrate.

Fuel type Production & delivery Delivered energy Transport Feedstock energy Total energy energy
Electricity/MJ 8.49   3.88   0.08   0.00   12.45
Oil fuels/MJ 0.53   2.66   1.05   0.00   4.24
Other fuels/MJ 1.03   16.63   0.01   0.10 17.77
Total/MJ 10.05   23.17   1.14   0.10   34.46

5.2. Primary fuels

The cumulative primary fuel and feedstock requirements for the production of sodium perborate tetrahydrate are given in Table 3. The equivalent data for the monohydrate is shown in Table 4.

Table 3.
Gross primary energy associated with the production of 1 kg of sodium perborate tetrahydrate. (Totals may not agree because of rounding)

   Fuel production Fuel use Transport Feedstock Total
Coal 1.42 1.00 0.02 <0.01 2.44
Oil 0.80 1.14 0.65 0.02 2.61
Gas 0.90 6.89 0.03 0.05 7.87
Hydro 0.20 0.16 <0.01 - 0.36
Nuclear 1.40 0.84 0.01 - 2.25
Lignite 0.14 0.07 <0.01 - 0.22
Wood <0.01 0.01 - - 0.01
Sulphur <0.01 0.02 <0.01 <0.01 0.02
Hydrogen - 0.07 - - 0.07
Recovered <0.01 - 1.07 <0.01 - -1.07
Peat <0.01 0.06 - - 0.06
Total 4.87 9.19 0.71 0.07 14.83

Table 4.
Gross primary energy associated with the production of 1 kg of sodium perborate monohydrate. (Totals may not agree because of rounding)

   Fuel production Fuel use Transport Feedstock Total
Coal 2.78 2.15 0.03 <0.01 4.97
Oil 1.65 3.04 1.05 0.00 5.75
Gas 1.87 17.10 0.04 0.10 19.11
Hydro 0.51 0.42 <0.01 - 0.93
Nuclear 2.93 1.65 0.01 - 4.60
Lignite 0.30 0.17 <0.01 - 0.46
Wood <0.01 0.01 - - 0.02
Sulphur <0.01 0.04 <0.01 <0.01 0.04
Hydrogen - 0.17 - - 0.17
Recovered <0.01 -1.67 <0.01 - - 1.67
Peat 0.01 0.09 - - 0.10
Total 10.05 23.17 1.14 0.10 34.46

5.3. Air emissions

The gross or cumulative air emissions associated with all operations up to and including the production of sodium perborate tetrahydrate is shown in Table 5. Table 6 gives the corresponding air emission data for the production of the monohydrate.

Table 5.
Gross air emissions associated with the production of 1 kg of sodium perborate tetrahydrate. (Totals may not agree because of rounding).

Air emission in mg Fuel production Fuel use Transport Process Biomass Total
Dust 860 430 15 1 500 - 2 800
CO 120 72 120 130 - 439
CO2 240 000 440 000 46 000 160 000 840 890 000
SOx 2 400 900 720 1 400 - 5 500
NOx   1 100 4 200 300 1 000 - 6 600
N2O   <1 - - - - <1
Hydrocarbons 300 560 89 920 - 1 900
Methane 3 900 1 900 - <1 - 5 800
H2S - - - <1 - <1
HCl 29 <1 - 22 - 51
Cl2 - - - <1 - <1
HF 1 <1 - <1 - 1
Metals <1 19 - <1 - 20
F2 - - - <1 - <1
Mercaptans - <1 - - - <1
Organo-Cl - - - <1 - <1
Aromatic HC - - - 39 - 39
Other organics - - - 120 - 120
NH3 - - - <1 - <1
Hydrogen - - - 96 - 96

Table 6.
Gross air emissions associated with the production of 1 kg of sodium perborate monohydrate. (Totals may not agree because of rounding).

Air emission in mg Fuel production Fuel use Transport Process Biomass Total
Dust 1 900 1 100 25 2 700 - 5 700
CO 260 150 200 250 - 860
CO2 520 000 1 200 000 74 000 260 000 1 300 2 100 000
SOx 5 500 2 900 1 100 2 300 - 12 000
NOx 2 600 11 000 490 1 600 - 15 000
N2O <1 - - - - <1
Hydrocarbons 740 950 140 1 500 - 3 300
Methane 9 000 5 300 - 1 - 14 000
H2S   - - - <1 - <1
HCl 61 <1 - 35 - 96
Cl2 - - - <1 - <1
HF 3 <1 - <1 - 3
Metals 1 70 - <1 - 71
F2 - - - <1 - <1
Mercaptans - <1 - - - <1
Organo-Cl - - - <1 - <1
Aromatic HC - - - 64 - 64
Other organics   - - - 120 - 120
NH3 - - - <1 - <1
Hydrogen - - - 150 - 150

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